Home > Publications database > Glycogen-graft-poly(2-alkyl-2-oxazolines) - The new Versatile Biopolymer-Based Thermoresponsive Macromolecular Toolbox > print |
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100 | 1 | _ | |a Pospisilova, Aneta |0 P:(DE-HGF)0 |b 0 |e Corresponding Author |
245 | _ | _ | |a Glycogen-graft-poly(2-alkyl-2-oxazolines) - The new Versatile Biopolymer-Based Thermoresponsive Macromolecular Toolbox |
260 | _ | _ | |a London |c 2014 |b RSC Publishing |
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520 | _ | _ | |a his study is focused on thermoresponsive glycogen-graft-poly(2-alkyl-2-oxazolines), a new group of nanostructured hybrid dendrimeric stimuli-responsive polymers connecting the body's own biodegradable polysaccharidic dendrimer glycogen with the widely tuneable thermoresponsive behavior of polypeptide-analogic poly(2-alkyl-2-oxazolines), which are known to be biocompatible. Glycogen-graft-poly(2-alkyl-2-oxazolines) were prepared by a simple one-pot two-step procedure involving cationic ring-opening polymerization of 2-alkyl-2-oxazolines followed by termination of the living cationic ends with sodium glycogenate. As confirmed by light and X-ray scattering, as well as cryo-transmission electron microscopy, the grafted dendrimer structure allows easy adjustment of the cloud point temperature, the concentration dependence and nanostructure of the self-assembled phase separated polymer by crosstalk during graft composition, the graft length and the grafting density, in a very wide range. |
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773 | _ | _ | |a 10.1039/c4ra10315g |0 PERI:(DE-600)2623224-8 |p 61580-61588 |t RSC Advances |v 4 |y 2014 |x 2046-2069 |
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