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@ARTICLE{Wojtczak:205784,
author = {Wojtczak, Malgorzata and Galeski, Andrzej and Dutkiewicz,
Slawomir and Piorkowska, Ewa},
title = {{T}he {I}nfluence of {C}hemical {C}omposition of
{A}liphatic-{A}romatic {C}opolyesters on their {P}roperties},
journal = {AIP conference proceedings},
volume = {1599},
issn = {0094-243X},
address = {Melville, NY},
publisher = {Inst.},
reportid = {PUBDB-2015-00322},
pages = {214-217},
year = {2014},
note = {(c) AIP Publishing LLC},
abstract = {The chain microstructure and properties of a series of
aliphatic-aromatic copolyesters in a range of compositions
from 10 to $100\%$ of aromatic components were studied by
examining melting and crystallization behaviors, dynamic
mechanical response, morphology, wide- (WAXS) and
small-angle X-ray scattering (SAXS), and tensile
deformation. Chain microstructure was analyzed by $^{1}H$
NMR. The results indicate that most of copolyesters used in
this study have essentially random distribution of
comonomers. Copolyesters with more than 30 mol\% of aromatic
part crystallize with a crystal structure characteristic for
homopolymer poly(butylene terephthalate) (PBT). However,
some of the reflections from crystal planes are shifted
towards lower diffraction angles as compared to butylene
terephthalate homoplymer. The phase transition temperatures
decrease with increasing aliphatic content. By means of
polarized light microscopy (PLM), small-angle light
scattering (SALS) and SAXS, crystallization behavior of a
selected aliphatic-aromatic copolyester was further
explored. Selected copolyester crystallizes in the form of
thin fibrous crystals, few nanometers thick, which is the
main factor influencing the depression of its melting
temperature.},
organization = {TIMES OF POLYMERS (TOP) AND COMPOSITES
2014: Proceedings of the 7th
International Conference on Times of
Polymers (TOP) and Composites, Ischia
(Italy)},
cin = {DOOR},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {DORIS Beamline A2 (POF2-54G13) / FS-Proposal: I-20110505 EC
(I-20110505-EC)},
pid = {G:(DE-H253)POF2-A2-20130405 / G:(DE-H253)I-20110505-EC},
experiment = {EXP:(DE-H253)D-A2-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000341451600054},
doi = {10.1063/1.4876816},
url = {https://bib-pubdb1.desy.de/record/205784},
}