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000205613 1001_ $$0P:(DE-H253)PIP1007782$$aMedyanik, Katerina$$b0$$eCorresponding Author
000205613 245__ $$aHard X-ray photoemission study of the Fabre salts $\mathrm{(TMTTF)_2X (X = SbF_6}$ and $\mathrm{PF_6)}$
000205613 260__ $$aBerlin$$bSpringer$$c2014
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000205613 520__ $$aCore-level photoemission spectra of the Fabre salts with X = SbF6 and PF6 were taken using hard X-rays from PETRA III, Hamburg. In these salts TMTTF layers show a significant stack dimerization with a charge transfer of 1e per dimer to the anion SbF6 or PF6 . At room temperature and slightly below the core-level spectra exhibit single lines, characteristic for a well-screened metallic state. At reduced temperatures progressive charge localization sets in, followed by a 2nd order phase transition into a charge-ordered ground state. In both salts groups of new core-level signals occur, shifted towards lower kinetic energies. This is indicative of a reduced transverse-conductivity across the anion layers, visible as layer-dependent charge depletion for both samples. The surface potential was traced via shifts of core-level signals of an adsorbate. A well-defined potential could be established by a conducting cap layer of 5 nm aluminum which appears “transparent” due to the large probing depth of HAXPES (8–10 nm). At the transition into the charge-ordered phase the fluorine 1s line of (TMTTF)2 SbF6 shifts by 2.8 eV to higher binding energy. This is a spectroscopic fingerprint of the loss of inversion symmetry accompanied by a cooperative shift of the SbF6 anions towards the more positively charged TMTTF donors. This shift does not occur for the X = PF6 compound, most likely due to smaller charge disproportion or due to thepresence of charge disorder.
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000205613 7001_ $$0P:(DE-H253)PIP1013093$$ade Souza, Mariano$$b1
000205613 7001_ $$0P:(DE-HGF)0$$aKutnyakhov, Dmytro$$b2
000205613 7001_ $$0P:(DE-H253)PIP1007694$$aGloskovskii, Andrei$$b3
000205613 7001_ $$0P:(DE-H253)PIP1001886$$aMüller, Jens$$b4
000205613 7001_ $$0P:(DE-HGF)0$$aLang, Michael$$b5
000205613 7001_ $$0P:(DE-HGF)0$$aPouget, Jean-Paul$$b6
000205613 7001_ $$0P:(DE-HGF)0$$aFoury-Leylekian, Pascale$$b7
000205613 7001_ $$0P:(DE-HGF)0$$aMoradpour, Alec$$b8
000205613 7001_ $$0P:(DE-H253)PIP1015647$$aElmers, Hans-Joachim$$b9
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000205613 773__ $$0PERI:(DE-600)1459068-2$$a10.1140/epjb/e2014-50499-y$$gVol. 87, no. 11, p. 256$$n11$$p256$$tThe @European physical journal / B$$v87$$x1434-6028$$y2014
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