% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Schweinefuss:192607,
      author       = {Schweinefuss, Maria and Baburin, Igor A. and Schroeder,
                      Christian and Näther, Christian and Leoni, Stefano and
                      Wiebcke, Michael},
      title        = {{I}ndium {I}midazolate {F}rameworks with {D}ifferently
                      {D}istorted ${R}e{O}_{3}$-{T}ype {S}tructures: {S}yntheses,
                      {S}tructures, {P}hase {T}ransitions, and {C}rystallization
                      {S}tudies},
      journal      = {Crystal growth $\&$ design},
      volume       = {14},
      number       = {9},
      issn         = {1528-7483},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PUBDB-2014-04189},
      pages        = {4664-4673},
      year         = {2014},
      abstract     = {Three indium imidazolates have been preparedby employing
                      solvothermal, ionothermal, and solventlesssyntheses. The
                      crystal structures have been determined usinglaboratory
                      powder XRD methods in combination with DFTcalculations. In
                      phases I−III, octahedrally coordinated In(III)ions are
                      bridged by imidazolate (im) ligands into 3Dframeworks that
                      are related to distorted filled-ReO3 (ABX3perovskite)
                      structures with different octahedron tilting.Clathrate-type
                      phases I (cubic space group Im3̅) and II(trigonal R3̅) may
                      be formulated as [A′A″3In4(im)12] andcontain two types
                      of cubic cages, A′ and A″, which may hostguest molecules
                      and are occupied by im moieties, respectively. A reversible
                      structural phase transition between low-temperaturephase II
                      and high-temperature phase I, occurring on heating at about
                      90 °C, was studied by DSC and variable-temperaturepowder
                      XRD experiments. Depending on the synthesis, more
                      specifically on the nature and amount of guests trapped in
                      the A′cages, the phase transition was suppressible,
                      enabling I to be recovered at room temperature. Phase III
                      (trigonal R3̅) may beformulated as [AIn(im)3]. It is a
                      dense phase in which the cubic A cages are occupied by im
                      moieties. For the first time, theionothermal formation of a
                      coordination polymer, phase III, was monitored in situ by
                      time-resolved EDXRD experiments. Rateconstants and
                      activation energies for both nucleation and crystal growth,
                      as estimated by kinetic analysis of the EDXRD data,
                      arecompared to corresponding values reported previously for
                      the solvothermal crystallization of other coordination
                      polymers.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {DORIS Beamline F3 (POF2-54G13) / FS-Proposal: I-20110615
                      (I-20110615)},
      pid          = {G:(DE-H253)POF2-F3-20130405 / G:(DE-H253)I-20110615},
      experiment   = {EXP:(DE-H253)D-F3-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000341226500051},
      doi          = {10.1021/cg5007499},
      url          = {https://bib-pubdb1.desy.de/record/192607},
}