000172563 001__ 172563
000172563 005__ 20250717112635.0
000172563 0247_ $$2doi$$a10.1063/1.4895672
000172563 0247_ $$2ISSN$$a1077-3118
000172563 0247_ $$2ISSN$$a0003-6951
000172563 0247_ $$2WOS$$aWOS:000342758700057
000172563 0247_ $$2altmetric$$aaltmetric:2680785
000172563 0247_ $$2openalex$$aopenalex:W2042136016
000172563 037__ $$aPUBDB-2014-03799
000172563 082__ $$a530
000172563 1001_ $$0P:(DE-HGF)0$$aChaturvedi, Smita$$b0
000172563 245__ $$aProbing bismuth ferrite nanoparticles by hard X-ray photoemission: Anomalous occurrence of metallic bismuth
000172563 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2014
000172563 3367_ $$2DRIVER$$aarticle
000172563 3367_ $$2DataCite$$aOutput Types/Journal article
000172563 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1597845416_3221
000172563 3367_ $$2BibTeX$$aARTICLE
000172563 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000172563 3367_ $$00$$2EndNote$$aJournal Article
000172563 500__ $$3POF3_Assignment on 2016-02-15
000172563 500__ $$3POF3_Prefill: G:(DE-HGF)POF3-6214
000172563 500__ $$aOA
000172563 520__ $$aWe have investigated bismuth ferrite nanoparticles (∼75 nm and ∼155 nm) synthesized by a chemical method, using soft X-ray (1253.6 eV) and hard X-ray (3500, 5500, and 7500 eV) photoelectron spectroscopy. This provided an evidence for the variation of chemical state of bismuth in crystalline, phase pure nanoparticles. X-ray photoelectron spectroscopy analysis using Mg Kα (1253.6 eV) source showed that iron and bismuth were present in both Fe3+ and Bi3+ valence states as expected for bismuth ferrite. However, hard X-ray photoelectron spectroscopy analysis of the bismuth ferrite nanoparticles using variable photon energies unexpectedly showed the presence of Bi0 valence state below the surface region, indicating that bismuth ferrite nanoparticles are chemically inhomogeneous in the radial direction. Consistently, small-angle X-ray scattering reveals a core-shell structure for these radial inhomogeneous nanoparticles.
000172563 536__ $$0G:(DE-H253)POF2-P09-20130405$$aPETRA Beamline P09 (POF2-54G14)$$cPOF2-54G14$$fPOF II$$x0
000172563 536__ $$0G:(DE-HGF)2020_Join2-INDIA-DESY$$aINDIA-DESY - INDIA-DESY Collaboration (2020_Join2-INDIA-DESY)$$c2020_Join2-INDIA-DESY$$x1
000172563 588__ $$aDataset connected to CrossRef, bib-pubdb1.desy.de
000172563 693__ $$0EXP:(DE-H253)P-P09-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P09-20150101$$aPETRA III$$fPETRA Beamline P09$$x0
000172563 7001_ $$0P:(DE-H253)PIP1017340$$aSarkar, Indranil$$b1$$udesy
000172563 7001_ $$0P:(DE-HGF)0$$aShirolkar, Mandar M.$$b2
000172563 7001_ $$0P:(DE-HGF)0$$aJeng, U-Ser$$b3
000172563 7001_ $$0P:(DE-HGF)0$$aYeh, Yi-Qi$$b4
000172563 7001_ $$0P:(DE-HGF)0$$aRajendra, Ranguwar$$b5
000172563 7001_ $$0P:(DE-H253)PIP1015313$$aBallav, Nirmalya$$b6
000172563 7001_ $$0P:(DE-H253)PIP1015207$$aKulkarni, Sulabha$$b7$$eCorresponding Author
000172563 773__ $$0PERI:(DE-600)1469436-0$$a10.1063/1.4895672$$gVol. 105, no. 10, p. 102910 -$$n10$$p102910$$tApplied physics letters$$v105$$x1077-3118$$y2014
000172563 8564_ $$uhttps://bib-pubdb1.desy.de/record/172563/files/PUBDB-2014-03799.pdf$$yOpenAccess
000172563 8564_ $$uhttps://bib-pubdb1.desy.de/record/172563/files/PUBDB-2014-03799.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000172563 8564_ $$uhttps://bib-pubdb1.desy.de/record/172563/files/PUBDB-2014-03799.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000172563 8564_ $$uhttps://bib-pubdb1.desy.de/record/172563/files/PUBDB-2014-03799.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000172563 909CO $$ooai:bib-pubdb1.desy.de:172563$$pdnbdelivery$$pdriver$$popenaire$$popen_access$$pVDB
000172563 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1017340$$aDeutsches Elektronen-Synchrotron$$b1$$kDESY
000172563 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1015313$$aExternes Institut$$b6$$kExtern
000172563 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1015207$$aExternes Institut$$b7$$kExtern
000172563 9132_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6214$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000172563 9132_ $$0G:(DE-HGF)POF3-622$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6G3$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Research on Matter with Brilliant Light Sources$$x1
000172563 9131_ $$0G:(DE-HGF)POF2-54G14$$1G:(DE-HGF)POF2-540$$2G:(DE-HGF)POF2-500$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$9G:(DE-H253)POF2-P09-20130405$$aDE-H253$$bStruktur der Materie$$lForschung mit Photonen, Neutronen, Ionen$$vPETRA III$$x0
000172563 9141_ $$y2014
000172563 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000172563 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000172563 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000172563 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000172563 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000172563 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000172563 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000172563 915__ $$0StatID:(DE-HGF)0400$$2StatID$$aAllianz-Lizenz / DFG
000172563 915__ $$0LIC:(DE-HGF)AIP-04102013$$2HGFVOC$$aAmerican Institute of Physics web posting guidelines
000172563 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000172563 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000172563 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000172563 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000172563 9201_ $$0I:(DE-H253)FS-PEX-20130206$$kFS-PEX$$lPETRA III Extension$$x0
000172563 980__ $$ajournal
000172563 980__ $$aVDB
000172563 980__ $$aI:(DE-H253)FS-PEX-20130206
000172563 980__ $$aUNRESTRICTED
000172563 9801_ $$aFullTexts