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@ARTICLE{Michels:171851,
      author       = {Michels, Rolf and Goerigk, Günter and Vainio, Ulla and
                      Gummel, Jérémie and Huber, Klaus},
      title        = {{C}oaggregation of {T}wo {A}nionic {A}zo {D}yestuffs: {A}
                      {C}ombined {S}tatic {L}ight {S}cattering and {S}mall-{A}ngle
                      {X}-ray {S}cattering {S}tudy},
      journal      = {The journal of physical chemistry / B},
      volume       = {118},
      number       = {27},
      issn         = {1520-6106},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {DESY-2014-03392},
      pages        = {7618 - 7629},
      year         = {2014},
      abstract     = {The formation of azo dyestuff aggregates in dilute aqueous
                      solution induced by the addition of Mg2+, Ca2+, Sr2+, or
                      Ba2+ ions is followed by time-resolved static light
                      scattering (SLS) and time-resolved small-angle X-ray
                      scattering (SAXS). Time-dependent molar mass data of the
                      growing aggregates is interpreted by means of a kinetic
                      model introduced by Lomakin et al. ( Proc. Natl. Acad. Sci.
                      U.S.A. 1996, 93, 1125) for the description of β-amyloid
                      aggregation. This interpretation reveals significant trends
                      within the homologous series of alkaline earth cations. The
                      trends refer to the nucleation and the growth rate of the
                      dyestuff fibers. Time-resolved SAXS experiments indicate
                      that these first two stages are followed by a third one
                      during which a network forms by partial lateral alignment of
                      fibers. At high enough dyestuff concentrations, this network
                      formation even leads to a gel-like phase. Anomalous SAXS
                      (ASAXS) on such a gel phase formed upon the addition of Sr2+
                      revealed the extent of neutralization of the dyestuff
                      molecules within the gel by the specifically interacting
                      alkaline earth cations.},
      cin          = {FS-DO / DOOR / HZG},
      ddc          = {530},
      cid          = {I:(DE-H253)FS-DO-20120731 / I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)HZG-20120731},
      pnm          = {DORIS Beamline B1 (POF2-54G13)},
      pid          = {G:(DE-H253)POF2-B1-20130405},
      experiment   = {EXP:(DE-H253)D-B1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000338981200016},
      pubmed       = {pmid:24937796},
      doi          = {10.1021/jp502347b},
      url          = {https://bib-pubdb1.desy.de/record/171851},
}