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001     170905
005     20250717112649.0
024 7 _ |a 10.1111/jace.12823
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024 7 _ |a 0002-7820
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024 7 _ |a 1551-2916
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037 _ _ |a DESY-2014-03071
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100 1 _ |a Jóvári, Pál
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245 _ _ |a Short-Range Order in Ge-As-Te Glasses
260 _ _ |a Oxford [u.a.]
|c 2014
|b Wiley-Blackwell
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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520 _ _ |a The structure of Te-rich (75–80 at.% Te) and Te-poor (40 at.% Te) Ge–As–Te glasses has been investigated by diffraction and extended X-ray absorption fine structure (EXAFS) measurements. Large-scale structural models have been created by fitting simultaneously diffraction and EXAFS datasets by the reverse Monte Carlo simulation technique. It is found that As–As bonds improve the fit quality in the case of Te-rich glasses while no Ge–Ge bonding is necessary in these compositions. In the Te-poor glasses, Te–Te homopolar bonds are also observed while Ge binds preferentially to Te rather than to As. Ge–As and Ge–Te coordination numbers do not change significantly with increasing Ge content.
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700 1 _ |a Lucas, Pierre
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700 1 _ |a Yang, Zhiyong
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700 1 _ |a Bureau, Bruno
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700 1 _ |a Kaban, Ivan
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700 1 _ |a Beuneu, Brigitte
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700 1 _ |a Bednarčik, Jozef
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773 _ _ |a 10.1111/jace.12823
|g Vol. 97, no. 5, p. 1625 - 1632
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|t Journal of the American Ceramic Society
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|y 2014
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