000170905 001__ 170905 000170905 005__ 20250717112649.0 000170905 0247_ $$2doi$$a10.1111/jace.12823 000170905 0247_ $$2ISSN$$a0002-7820 000170905 0247_ $$2ISSN$$a1551-2916 000170905 0247_ $$2WOS$$aWOS:000335809400046 000170905 0247_ $$2openalex$$aopenalex:W2134581292 000170905 037__ $$aDESY-2014-03071 000170905 041__ $$aEnglish 000170905 082__ $$a660 000170905 1001_ $$0P:(DE-H253)PIP1007402$$aJóvári, Pál$$b0$$eCorresponding Author 000170905 245__ $$aShort-Range Order in Ge-As-Te Glasses 000170905 260__ $$aOxford [u.a.]$$bWiley-Blackwell$$c2014 000170905 3367_ $$00$$2EndNote$$aJournal Article 000170905 3367_ $$2DRIVER$$aarticle 000170905 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1434022159_24415 000170905 3367_ $$2BibTeX$$aARTICLE 000170905 500__ $$3POF3_Assignment on 2016-02-09 000170905 520__ $$aThe structure of Te-rich (75–80 at.% Te) and Te-poor (40 at.% Te) Ge–As–Te glasses has been investigated by diffraction and extended X-ray absorption fine structure (EXAFS) measurements. Large-scale structural models have been created by fitting simultaneously diffraction and EXAFS datasets by the reverse Monte Carlo simulation technique. It is found that As–As bonds improve the fit quality in the case of Te-rich glasses while no Ge–Ge bonding is necessary in these compositions. In the Te-poor glasses, Te–Te homopolar bonds are also observed while Ge binds preferentially to Te rather than to As. 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