Home > Publications database > pH controlled condensation of polysiloxane networks at the water-air interface > print |
001 | 168997 | ||
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100 | 1 | _ | |a Wieland, D. C. Florian |0 P:(DE-HGF)0 |b 0 |e Corresponding Author |
245 | _ | _ | |a pH controlled condensation of polysiloxane networks at the water-air interface |
260 | _ | _ | |a Amsterdam [u.a.] |c 2014 |b Elsevier Science |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a article |2 DRIVER |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1407154772_17443 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
500 | _ | _ | |3 POF3_Assignment on 2016-02-09 |
520 | _ | _ | |a Structural and mechanical properties of molecularly thick polysiloxane membranes were studied on different liquid subphases to investigate the impact of the subphase's pH value on the cross-linking process. The lateral structure of these films was studied in-situ by grazing incidence diffraction while torsions pendulum experiments reveal the response of the system to mechanical stress. The results show a hindered cross-linking on acidic subphases. At alkaline and neutral pH conditions the cross-linking process was not effected. The data revealed that the degree of polymerization can be tuned by regulating the subphase's pH value, which opens the opportunity to build complex polysiloxane membranes in a controlled manner. |
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700 | 1 | _ | |a Degen, Patrick |0 P:(DE-H253)PIP1009560 |b 1 |
700 | 1 | _ | |a Paulus, M. |0 P:(DE-H253)PIP1007931 |b 2 |
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773 | _ | _ | |a 10.1016/j.colsurfa.2014.03.099 |0 PERI:(DE-600)1500517-3 |p 44-48 |t Colloids and surfaces / A |v 455 |y 2014 |x 0927-7757 |
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