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@ARTICLE{Sarapulova:168084,
      author       = {Sarapulova, A. E. and Bazarov, B. and Namsaraeva, T. and
                      Dorzhieva, S. and Bazarova, J. and Grossman, V. and Bush, A.
                      A. and Antonyshyn, I. and Schmidt, M. and Bell, A. M. T. and
                      Knapp, Michael and Ehrenberg, H. and Eckert, J. and
                      Mikhailova, D.},
      title        = {{P}ossible {P}iezoelectric {M}aterials
                      ${C}s{MZ}r_{0.5}({M}o{O}_{4})_{3}$ ( {M} = {A}l, {S}c, {V},
                      {C}r, {F}e, {G}a, {I}n) and
                      ${C}s{C}r{T}i_{0.5}({M}o{O}_{4})_{3}$: {S}tructure and
                      {P}hysical {P}roperties},
      journal      = {The journal of physical chemistry / C},
      volume       = {118},
      number       = {4},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {DESY-2014-02330},
      pages        = {1763 - 1773},
      year         = {2014},
      abstract     = {A series of isostructural trigonal molybdates
                      CsMZr0.5(MoO4)(3) with M = Al, Ga, In, Sc, Cr, V, Fe, and
                      CsCrTi0.5(MoO4)(3) was synthesized by solid state reactions
                      and characterized by synchrotron powder diffraction,
                      differential scanning calorimetry, thermal conductivity
                      measurements, and magnetization measurements for compounds
                      with a magnetic 3d transition metal cation. The NASICON-type
                      structure of these compounds represents a three-dimensional
                      framework of corner-sharing trigonal MoO4-pyramids and
                      MO6-octahedra, in which M and Zr (Ti) ions are randomly
                      distributed. The Cs ions occupy large channels along the
                      c-axis. A combination of phenomena like a drastic increase
                      of thermal conductivity, endothermic signals in the DSC
                      curve and anomalies in the thermal expansion coefficients,
                      observed for the compounds with M = Cr, V, Fe, and
                      CsCrTi0.3(MoO4)(3) above 700 K, allows one to propose a
                      structural phase transition. The crystal structure of the
                      high-temperature phase is very close to the low-temperature
                      one. A significant hysteresis in high-temperature electronic
                      and thermal conductivity was observed. A possible transition
                      from the piezoelectric to the paraelectric state is
                      discussed.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {DORIS Beamline B2 (POF2-54G13)},
      pid          = {G:(DE-H253)POF2-B2-20130405},
      experiment   = {EXP:(DE-H253)D-B2-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000330610200002},
      doi          = {10.1021/jp4077245},
      url          = {https://bib-pubdb1.desy.de/record/168084},
}