000167945 001__ 167945
000167945 005__ 20250730143839.0
000167945 0247_ $$2doi$$a10.1063/1.4863446
000167945 0247_ $$2ISSN$$a1089-7690
000167945 0247_ $$2ISSN$$a0021-9606
000167945 0247_ $$2WOS$$aWOS:000331289200025
000167945 0247_ $$2pmid$$apmid:24511939
000167945 0247_ $$2openalex$$aopenalex:W1971735121
000167945 037__ $$aDESY-2014-02247
000167945 041__ $$aEnglish
000167945 082__ $$a540
000167945 1001_ $$0P:(DE-HGF)0$$aChadwick, H.$$b0$$eCorresponding author
000167945 245__ $$aThe collisional depolarization of OH$(A{}^2\Sigma^+)$ and NO$(A{}^2\Sigma^+)$ with Kr
000167945 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2014
000167945 3367_ $$2DRIVER$$aarticle
000167945 3367_ $$2DataCite$$aOutput Types/Journal article
000167945 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1481034055_12010
000167945 3367_ $$2BibTeX$$aARTICLE
000167945 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000167945 3367_ $$00$$2EndNote$$aJournal Article
000167945 500__ $$3POF3_Assignment on 2016-02-09
000167945 500__ $$3POF3_Prefill: G:(DE-HGF)POF3-6211
000167945 500__ $$a(c) AIP Publishing LLC
000167945 520__ $$aQuantum beat spectroscopy has been used to measure rate coefficients at 300 K for collisional depolarization for NO(A (2)Σ(+)) and OH(A (2)Σ(+)) with krypton. Elastic depolarization rate coefficients have also been determined for OH(A) + Kr, and shown to make a much more significant contribution to the total depolarization rate than for NO(A) + Kr. While the experimental data for NO(A) + Kr are in excellent agreement with single surface quasiclassical trajectory (QCT) calculations carried out on the upper 2A(') potential energy surface, the equivalent QCT and quantum mechanical calculations cannot account for the experimental results for OH(A) + Kr collisions, particularly at low N. This disagreement is due to the presence of competing electronic quenching at low N, which requires a multi-surface, non-adiabatic treatment. Somewhat improved agreement with experiment is obtained by means of trajectory surface hopping calculations that include non-adiabatic coupling between the ground 1A(') and excited 2A(') states of OH(X/A) + Kr, although the theoretical depolarization cross sections still significantly overestimate those obtained experimentally.
000167945 536__ $$0G:(DE-H253)POF2-CFEL-Exp.-20130405$$aExperiments at CFEL (POF2-544)$$cPOF2-544$$fPOF II$$x0
000167945 536__ $$0G:(DE-H253)POF2-Other-Beam-20130405$$aFS In-house research / external facilities (POF2-544)$$cPOF2-544$$fPOF II$$x1
000167945 536__ $$0G:(EU-Grant)238671$$aICONIC - Imaging and CONtrol In Chemistry - ICONIC (238671)$$c238671$$fFP7-PEOPLE-ITN-2008$$x2
000167945 588__ $$aDataset connected to CrossRef, bib-pubdb1.desy.de
000167945 693__ $$0EXP:(DE-H253)CFEL-Exp-20150101$$5EXP:(DE-H253)CFEL-Exp-20150101$$eExperiments at CFEL$$x0
000167945 693__ $$0EXP:(DE-MLZ)External-20140101$$5EXP:(DE-MLZ)External-20140101$$eMeasurement at external facility$$x1
000167945 7001_ $$0P:(DE-HGF)0$$aBrouard, M.$$b1
000167945 7001_ $$0P:(DE-H253)PIP1013772$$aChang, Y.-P.$$b2
000167945 7001_ $$0P:(DE-HGF)0$$aEyles, C. J.$$b3
000167945 7001_ $$0P:(DE-HGF)0$$aMcCrudden, G.$$b4
000167945 7001_ $$0P:(DE-HGF)0$$aPerkins, T.$$b5
000167945 7001_ $$0P:(DE-HGF)0$$aSeamons, S. A.$$b6
000167945 7001_ $$0P:(DE-HGF)0$$aKłos, J.$$b7
000167945 7001_ $$0P:(DE-HGF)0$$aAlexander, M. H.$$b8
000167945 7001_ $$0P:(DE-HGF)0$$aDagdigian, P. J.$$b9
000167945 7001_ $$0P:(DE-HGF)0$$aHerráez-Aguilar, D.$$b10
000167945 7001_ $$0P:(DE-HGF)0$$aAoiz, F. J.$$b11
000167945 773__ $$0PERI:(DE-600)1473050-9$$a10.1063/1.4863446$$gVol. 140, no. 5, p. 054306 -$$n5$$p054306 -$$tThe @journal of chemical physics$$v140$$x1089-7690$$y2014
000167945 8564_ $$uhttps://bib-pubdb1.desy.de/record/167945/files/DESY-2014-02247.pdf$$yOpenAccess
000167945 8564_ $$uhttps://bib-pubdb1.desy.de/record/167945/files/DESY-2014-02247.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000167945 8564_ $$uhttps://bib-pubdb1.desy.de/record/167945/files/DESY-2014-02247.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000167945 8564_ $$uhttps://bib-pubdb1.desy.de/record/167945/files/DESY-2014-02247.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000167945 909CO $$ooai:bib-pubdb1.desy.de:167945$$pdnbdelivery$$pec_fundedresources$$pVDB$$pdriver$$popen_access$$popenaire
000167945 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000167945 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000167945 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000167945 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000167945 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000167945 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000167945 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000167945 915__ $$0StatID:(DE-HGF)0400$$2StatID$$aAllianz-Lizenz / DFG
000167945 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000167945 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000167945 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000167945 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000167945 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000167945 9141_ $$y2014
000167945 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1013772$$aDeutsches Elektronen-Synchrotron$$b2$$kDESY
000167945 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1013772$$aCentre for Free-Electron Laser Science$$b2$$k>CFEL
000167945 9132_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6211$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000167945 9131_ $$0G:(DE-HGF)POF2-544$$1G:(DE-HGF)POF2-540$$2G:(DE-HGF)POF2-500$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$9G:(DE-H253)POF2-CFEL-Exp.-20130405$$aDE-H253$$bStruktur der Materie$$lForschung mit Photonen, Neutronen, Ionen$$vIn-house Research with PNI$$x0
000167945 9131_ $$0G:(DE-HGF)POF2-544$$1G:(DE-HGF)POF2-540$$2G:(DE-HGF)POF2-500$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$9G:(DE-H253)POF2-Other-Beam-20130405$$aDE-H253$$bStruktur der Materie$$lForschung mit Photonen, Neutronen, Ionen$$vIn-house Research with PNI$$x1
000167945 9201_ $$0I:(DE-H253)FS-CFEL-1-20120731$$kFS-CFEL-1$$lCFEL-Coherent X-Ray Imaging$$x0
000167945 9201_ $$0I:(DE-H253)FS-CFEL-CMI-20220405$$kFS-CFEL-CMI$$lCFEL-CMI$$x1
000167945 980__ $$ajournal
000167945 980__ $$aVDB
000167945 980__ $$aI:(DE-H253)FS-CFEL-1-20120731
000167945 980__ $$aI:(DE-H253)FS-CFEL-CMI-20220405
000167945 980__ $$aUNRESTRICTED
000167945 9801_ $$aFullTexts