% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Almasi:167941,
      author       = {Almasi, Miroslav and Zelenak, Vladimir and Opanasenko,
                      Maksym and Čejka, Jíří},
      title        = {{A} novel nickel metal–organic framework with
                      fluorite-like structure: gas adsorption properties and
                      catalytic activity in {K}noevenagel condensation},
      journal      = {Dalton transactions},
      volume       = {43},
      number       = {9},
      issn         = {1477-9234},
      address      = {London},
      publisher    = {RSC},
      reportid     = {DESY-2014-02243},
      pages        = {3730 - 3738},
      year         = {2014},
      note         = {(c) The Royal Society of Chemistry. 12 Monate Sperrfrist
                      für Post-referee version (bis Januar 2015). Code P.},
      abstract     = {A new non-interpenetrating 3D metal–organic framework
                      {[Ni4(μ6-MTB)2(μ2-H2O)4(H2O)4]·10DMF·11H2O}n (DMF =
                      N,N′-dimethylformamide) built from nickel(II) ions as
                      connectors and methanetetrabenzoate ligands (MTB4−) as
                      linkers has been synthesized and characterized. The single
                      crystal X-ray diffraction showed that complex exhibits
                      CaF2-like fluorite structure topology and four types of 3D
                      channels with sizes about 12.6 × 9.4 Å2, 9.4 × 8.0 Å2,
                      12.6 × 11.7 Å2 and 14.9 × 14.9 Å2, which are filled with
                      guest molecules. Conditions of the activation of the
                      compound have been studied and optimized by powder X-ray
                      diffraction during in situ heating, thermogravimetric
                      analysis and infrared spectroscopy. Nitrogen and carbon
                      dioxide adsorption showed that the activated sample exhibits
                      a BET specific surface area of 700 m2 g−1 and a carbon
                      dioxide uptake of 12.36 $wt\%$ at 0 °C, which are the
                      highest values reported for the compounds of the MTB4−
                      series. The complex was tested in Knoevenagel condensation
                      of aldehydes and active methylene compounds. Straightforward
                      dependence of the substrate conversion on the size of used
                      aldehyde was established. A possible mechanism of
                      Knoevenagel condensation over a MTB4− containing a
                      metal–organic framework was proposed.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {DORIS Beamline BW5 (POF2-54G13) / FS-Proposal: I-20110282
                      EC (I-20110282-EC)},
      pid          = {G:(DE-H253)POF2-BW5-20130405 / G:(DE-H253)I-20110282-EC},
      experiment   = {EXP:(DE-H253)D-BW5-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000331229200039},
      pubmed       = {pmid:24435475},
      doi          = {10.1039/c3dt52698d},
      url          = {https://bib-pubdb1.desy.de/record/167941},
}