%0 Journal Article
%A Almasi, Miroslav
%A Zelenak, Vladimir
%A Opanasenko, Maksym
%A Čejka, Jíří
%T A novel nickel metal–organic framework with fluorite-like structure: gas adsorption properties and catalytic activity in Knoevenagel condensation
%J Dalton transactions
%V 43
%N 9
%@ 1477-9234
%C London
%I RSC
%M DESY-2014-02243
%P 3730 - 3738 
%D 2014
%Z (c) The Royal Society of Chemistry. 12 Monate Sperrfrist für Post-referee version (bis Januar 2015). Code P.
%X A new non-interpenetrating 3D metal–organic framework [Ni4(μ6-MTB)2(μ2-H2O)4(H2O)4]·10DMF·11H2On (DMF = N,N′-dimethylformamide) built from nickel(II) ions as connectors and methanetetrabenzoate ligands (MTB4−) as linkers has been synthesized and characterized. The single crystal X-ray diffraction showed that complex exhibits CaF2-like fluorite structure topology and four types of 3D channels with sizes about 12.6 × 9.4 Å2, 9.4 × 8.0 Å2, 12.6 × 11.7 Å2 and 14.9 × 14.9 Å2, which are filled with guest molecules. Conditions of the activation of the compound have been studied and optimized by powder X-ray diffraction during in situ heating, thermogravimetric analysis and infrared spectroscopy. Nitrogen and carbon dioxide adsorption showed that the activated sample exhibits a BET specific surface area of 700 m2 g−1 and a carbon dioxide uptake of 12.36 wt
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000331229200039
%$ pmid:24435475
%R 10.1039/c3dt52698d
%U https://bib-pubdb1.desy.de/record/167941