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@ARTICLE{Almi:167939,
author = {Almáši, Miroslav and Zeleňák, Vladimír and Galdun,
Ladislav and Kuchár, Juraj},
title = {{F}irst 3{D} coordination polymer built from {H}o({III})
and 2-aminoterephthalate ligand},
journal = {Inorganic chemistry communications},
volume = {39},
issn = {1387-7003},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {DESY-2014-02241},
pages = {39 - 42},
year = {2014},
note = {(c) Elsevier B.V. Post referee fulltext in progress. Code
P.},
abstract = {Novel three-dimensional (3D) coordination polymer
{[Ho2(μ3-ATA)2(μ4-ATA)(H2O)4]·2DMF·1/2H2O}n (1), built
from Ho(III) cations and 2-aminoterephthalate anionic
ligands (ATA2 −) was prepared and studied. The compound 1
contains 1D structural channels with the size 4.1 × 6.8
Å2, which propagate along b crystallographic axis. The
channels are filled with the solvent molecules. The Ho(III)
atom is eight-coordinated with distorted square
anti-prismatic geometry. Complex was characterized by single
crystal X-ray diffraction, thermogravimetry coupled with
simultaneous evolved gas analysis using mass spectrometry
(TG/DTG–DTA–EGA), powder X-ray diffraction (PXRD),
infrared spectroscopy (FT-IR), solid-state UV–VIS
spectroscopy and nitrogen adsorption at 77 K. After the
desolvation the 1D structural channels collapse. The process
is accompanied by structure transformation, however,
according to the TG–DTA–EGA results, the Ho–ATA
polymeric framework is stable up to 450 °C.},
cin = {DOOR},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {DORIS Beamline BW5 (POF2-54G13) / FS-Proposal: I-20110282
EC (I-20110282-EC)},
pid = {G:(DE-H253)POF2-BW5-20130405 / G:(DE-H253)I-20110282-EC},
experiment = {EXP:(DE-H253)D-BW5-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000330157700009},
doi = {10.1016/j.inoche.2013.10.033},
url = {https://bib-pubdb1.desy.de/record/167939},
}