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@ARTICLE{Ahrens:167493,
author = {Ahrens, E. and Nitsche, F. and Doert, Th. and Ruck, M.},
title = {{S}ingle-crystal {X}-ray diffraction investigation of the
reversible order-disorder phase transition in iron-deficient
{T}l{F}e2-x{S}e2},
journal = {Crystal research and technology},
volume = {49},
number = {1},
issn = {0232-1300},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {DESY-2014-01835},
pages = {32 - 37},
year = {2014},
abstract = {A reversible phase transition was found for iron-deficient
TlFe2–xSe2 (x ≈ 0.4) and investigated on single crystals
using high temperature synchrotron radiation X-ray
diffraction. Full data sets have been collected at room
temperature and at 200°C to evaluate the structures. The
high-temperature form (space group I4/mmm, lattice
parameters a = 3.8919(3) Å, c = 14.027(3) Å) shows
complete statistical disorder of iron positions and
vacancies in a ThCr2Si2 type structure. The low-temperature
form corresponds to a √5×√5 superstructure of the
ThCr2Si2 type (I4/m, a = 8.6966(2) Å, c = 14.009(9) Å) and
shows partial ordering of iron positions and vacancies. A
group-subgroup relation can be compiled between both
structures.},
cin = {DOOR},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {DORIS Beamline D3 (POF2-54G13) / FS-Proposal: I-20110003
(I-20110003)},
pid = {G:(DE-H253)POF2-D3-20130405 / G:(DE-H253)I-20110003},
experiment = {EXP:(DE-H253)D-D3-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000337297500006},
doi = {10.1002/crat.201300223},
url = {https://bib-pubdb1.desy.de/record/167493},
}