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@ARTICLE{Sokolov:166699,
author = {Sokolov, V. I. and Pustovarov, Vladimir and Churmanov, V.
N. and Ivanov, Vladimir and Gruzdev, N. B. and Sokolov, Petr
and Baranov, Andrey and Moskvin, A. S.},
title = {{S}elf-trapping of the d-d charge transfer exciton in
rock-salt structured ${Z}n_{1-x}{N}i_{x}{O}$ evidenced by
soft {X}-ray excited luminescence},
journal = {Physica status solidi / C},
volume = {10},
number = {10},
issn = {1862-6351},
address = {Berlin},
publisher = {Wiley-VCH},
reportid = {DESY-2014-01540},
pages = {1329-1335},
year = {2013},
note = {© WILEY-VCH Verlag GmbH $\&$ Co. KGaA, Weinheim; Post
referee fulltext in progress; Embargo 12 months from
publication},
abstract = {Luminescence spectra of NiO and solid solutions Zn1–xNixO
have been investigated under vacuum ultra-violet (VUV) and
soft X-ray (XUV) excitation (DESY, Hamburg).
Photoluminescence (PL) spectra show broad emission violet
and green bands centered at about 3.2 and 2.6 eV,
respectively. The PL excitation (PLE) spec-tral evolution
and lifetime measurements reveal that the two mechanisms
with short and long decay times, at-tributed to the
d(eg)-d(eg) and p(π)-d charge transfer (CT) transitions in
the range 4–6 eV, respectively, are responsible for the
observed emissions. The XUV excitation makes it possible to
avoid the predominant role of the surface effects in
luminescence and reveal a bulk violet luminescence with
puzzling well isolated doublet of very narrow lines. These
lines with close energies near 3.3 eV are attributed to
recombination transitions in the self-trapped d-d CT
excitons formed by the coupled Jahn-Teller Ni+ and Ni3+
centers. (© 2013 WILEY-VCH Verlag GmbH $\&$ Co. KGaA,
Weinheim)},
cin = {DOOR},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {DORIS Beamline BW3 (POF2-54G13)},
pid = {G:(DE-H253)POF2-BW3-20130405},
experiment = {EXP:(DE-H253)D-BW3-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000337152100017},
doi = {10.1002/pssc.201200980},
url = {https://bib-pubdb1.desy.de/record/166699},
}