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@ARTICLE{Domesle:166388,
      author       = {Domesle, C. and Dziarzhytski, S. and Guerassimova, N. and
                      Harbo, L. S. and Heber, O. and Lammich, L. and
                      Jordon-Thaden, B. and Treusch, R. and Wolf, A. and Pedersen,
                      H. B.},
      title        = {{P}hotoionization and fragmentation of
                      $\mathrm{{H}_{3}{O}^{+}}$ under {XUV} irradiation},
      journal      = {Physical review / A},
      volume       = {88},
      number       = {4},
      issn         = {1050-2947},
      address      = {College Park, Md.},
      publisher    = {APS},
      reportid     = {DESY-2014-01301},
      pages        = {043405},
      year         = {2013},
      abstract     = {The photolysis of the hydronium cation H3O+ has been
                      studied at the extreme ultraviolet wavelengths of
                      35.56±0.24 nm (34.87±0.24 eV) and 21.85±0.17 nm
                      (56.74±0.44 eV) using a crossed ion-photon beam setup at
                      the free-electron laser FLASH. Coincidence photoelectron and
                      photofragment spectroscopy was performed at 21.85 nm, where
                      both inner and outer valence ionization are allowed, and
                      revealed that the XUV photolysis of H3O+ is by far dominated
                      by ionization of outer valence electrons forming the 1A1 and
                      2E states of the dication H3O2+. The dications were found to
                      dissociate into the channels H2O++H+ $(72±4\%),$ OH0+2H+
                      $(18±6\%),$ and OH++H++H0 $(10±1\%).$ A kinematic analysis
                      of the H2O++H+ channel after photoabsorption at 35.56 nm
                      (where only outer valence ionization is possible) showed
                      dissociation into excited states of the water radical ion,
                      where the 1A1 state breaks up into the linear A˜2A1 state
                      of H2O+ and the 2E state decays into the strongly bent
                      B˜2B2 state. Finally, from the 2E state of H3O2+,
                      dissociation into OH0(X2Π)+2H+ was identified to occur with
                      a near linear dissociation geometry.},
      cin          = {DOOR / FS-FL},
      ddc          = {530},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-FL-20120731},
      pnm          = {FLASH Beamline PG2 (POF2-54G16)},
      pid          = {G:(DE-H253)POF2-PG2-20130405},
      experiment   = {EXP:(DE-H253)F-PG2-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000325493800003},
      doi          = {10.1103/PhysRevA.88.043405},
      url          = {https://bib-pubdb1.desy.de/record/166388},
}