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@INPROCEEDINGS{Soru:155946,
      author       = {Soru, S. and Taras, A. and Pistidda, C. and Milanese, C.
                      and Bonatto Minella, C. and Masolo, E. and Nolis, P. and D.
                      Baró, M. and Marini, A. and Tolkiehn, M. and Dornheim, M.
                      and Enzo, S. and Mulas, G. and Garroni, S.},
      title        = {{S}tructural evolution upon decomposition of the
                      ${L}i{A}l{H}_{4}$ + ${L}i{BH}_{4}$ system},
      journal      = {Journal of alloys and compounds},
      issn         = {0925-8388},
      address      = {Lausanne},
      publisher    = {Elsevier},
      reportid     = {DESY-2013-01543},
      year         = {2013},
      note         = {(c) Elsevier B.V.},
      abstract     = {In the present work we focus the attention on the phase
                      structural transformations occurring upon the desorption
                      process of the LiBH4 + LiAlH4 system. This study is
                      conducted by means of manometric–calorimetric, in situ
                      Synchrotron Radiation Powder X-ray Diffraction (SR-PXD) and
                      exsitu Solid State Magic Angle Spinning (MAS) Nuclear
                      Magnetic Resonance (NMR) measurements. The desorption
                      reaction is characterized by two main dehydrogenation steps
                      starting at 320 and 380 °C, respectively. The first step
                      corresponds to the decomposition of LiAlH4 into Al and H2via
                      the formation of Li3AlH6 whereas the second one refers to
                      the dehydrogenation of LiBH4 (molten state). In the range
                      328–380 °C, the molten LiBH4 reacts with metallic Al
                      releasing hydrogen and forming an unidentified phase which
                      appears to be an important intermediate for the desorption
                      mechanism of LiBH4–Al-based systems. Interestingly, NMR
                      studies indicate that the unknown intermediate is stable up
                      to 400 °C and it is mainly composed of Li, B, Al and H. In
                      addition, the NMR measurements of the annealed powders (400
                      °C) confirm that the desorption reaction of the LiBH4 + Al
                      system proceeds via an amorphous boron compound.},
      month         = {Jun},
      date          = {2013-06-30},
      organization  = {20th International Symposium on
                       Metastable, Amorphous and
                       Nanostructured Materials, Turin
                       (Italy), 30 Jun 2013 - 5 Jul 2013},
      cin          = {HZG},
      ddc          = {670},
      cid          = {I:(DE-H253)HZG-20120731},
      pnm          = {DORIS Beamline D3 (POF2-54G13)},
      pid          = {G:(DE-H253)POF2-D3-20130405},
      experiment   = {EXP:(DE-H253)D-D3-20150101},
      typ          = {PUB:(DE-HGF)8 / PUB:(DE-HGF)16},
      UT           = {WOS:000343613600144},
      doi          = {10.1016/j.jallcom.2013.12.027},
      url          = {https://bib-pubdb1.desy.de/record/155946},
}