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024 7 _ |a 10.1021/ja4072139
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024 7 _ |a 1520-5126
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037 _ _ |a DESY-2013-01007
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100 1 _ |a Mondal, Kartik Chandra
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245 _ _ |a Formation of a 1,4-Diamino-2,3-disila-1,3-butadiene Derivative
260 _ _ |a Washington, DC
|c 2013
|b American Chemical Society
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520 _ _ |a A 1,4-diamino-2,3-disila-1,3-butadiene derivative of composition (Me2-cAAC)2(Si2Cl2) (Me2-cAAC = :C(CMe2)2(CH2)N-2,6-iPr2C6H3) was synthesized by reduction of the Me2-cAAC:SiCl4 adduct with KC8. This compound is stable at 0 °C for 3 months in an inert atmosphere. Theoretical studies reveal that the silicon atoms exhibit pyramidal coordination, where the Cl–Si–Si–Cl dihedral angle is twisted by 43.3° (calcd 45.9°). The two silicon–carbon bonds are intermediates between single and double Si–C bonds due to twisting of the C–Si–Si–C dihedral angle (163.6°).
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700 1 _ |a Roesky, Herbert W.
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700 1 _ |a Dittrich, Birger
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700 1 _ |a Holzmann, Nicole
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700 1 _ |a Hermann, Markus
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700 1 _ |a Frenking, Gernot
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700 1 _ |a Meents, Alke
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773 _ _ |a 10.1021/ja4072139
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