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@ARTICLE{Mondal:154648,
      author       = {Mondal, Kartik Chandra and Roesky, Herbert W. and Dittrich,
                      Birger and Holzmann, Nicole and Hermann, Markus and
                      Frenking, Gernot and Meents, Alke},
      title        = {{F}ormation of a 1,4-{D}iamino-2,3-disila-1,3-butadiene
                      {D}erivative},
      journal      = {Journal of the American Chemical Society},
      volume       = {135},
      number       = {43},
      issn         = {1520-5126},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {DESY-2013-01007},
      pages        = {15990 - 15993},
      year         = {2013},
      abstract     = {A 1,4-diamino-2,3-disila-1,3-butadiene derivative of
                      composition (Me2-cAAC)2(Si2Cl2) (Me2-cAAC =
                      :C(CMe2)2(CH2)N-2,6-iPr2C6H3) was synthesized by reduction
                      of the Me2-cAAC:SiCl4 adduct with KC8. This compound is
                      stable at 0 °C for 3 months in an inert atmosphere.
                      Theoretical studies reveal that the silicon atoms exhibit
                      pyramidal coordination, where the Cl–Si–Si–Cl dihedral
                      angle is twisted by 43.3° (calcd 45.9°). The two
                      silicon–carbon bonds are intermediates between single and
                      double Si–C bonds due to twisting of the C–Si–Si–C
                      dihedral angle (163.6°).},
      cin          = {FS-PE / DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-PE-20120731 / I:(DE-H253)HAS-User-20120731},
      pnm          = {PETRA Beamline P11 (POF2-54G14)},
      pid          = {G:(DE-H253)POF2-P11-20130405},
      experiment   = {EXP:(DE-H253)P-P11-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000326487800007},
      pubmed       = {pmid:24134747},
      doi          = {10.1021/ja4072139},
      url          = {https://bib-pubdb1.desy.de/record/154648},
}