Home > Publications database > Congruent melting and rapid single-crystal growth of ZnO at 4 GPa > print

001     152979
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100 1 _ |a Mukhanov, Vladimir A.
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245 _ _ |a Congruent melting and rapid single-crystal growth of ZnO at 4 GPa
260 _ _ |a London
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500 _ _ |a (c) The Royal Society Chemistry
520 _ _ |a Transparent, colorless and contamination-free ZnO single crystals have been grown by rapid crystallization from the melt at [similar]4 GPa and [similar]1700 K. Recovered crystals exhibit needle-like (along the [0001] direction) morphology and have sizes up to 2 mm in length and 0.2 mm dia. Wurtzite structure (P63mc) has been confirmed by single-crystal X-ray diffraction, and lattice parameters (a = 3.2474(5) Å, c = 5.2017(7) Å) are in good agreement with literature data. Photoluminescence measurements revealed an intensive violet line at 398 nm, whose intensity depends non-linearly on the laser excitation power due to collective effects in photoexcited charge carriers or/and an effect of the stimulated emission in the ZnO crystals under study.
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700 1 _ |a Sokolov, Petr
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700 1 _ |a Baranov, Andrey
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700 1 _ |a Timoshenko, Victor Yu.
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700 1 _ |a Zhigunov, Denis M.
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700 1 _ |a Solozhenko, Vladimir
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773 _ _ |a 10.1039/c3ce40766g
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