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@ARTICLE{Diethert:140186,
author = {Diethert, A. and Körstgens, V. and Magerl, D. and Ecker,
K. and Perlich, J. and Roth, S. V. and Müller-Buschbaum, P.
and DESY},
title = {{S}tructure and macroscopic tackiness of ultra-thin
pressure sensitive adhesive films},
journal = {ACS applied materials $\&$ interfaces},
volume = {4},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PHPPUBDB-23863},
pages = {3951-3958},
year = {2012},
abstract = {Ultrathin layers of the statistical copolymer
P(nBA-stat-MA) with a majority of n-butyl acrylate (nBA) and
a minority of methyl acrylate (MA) are characterized with
respect to the film morphology and the mechanical response
in a probe tack test. The probed copolymer can be regarded
as a model system of a pressure sensitive adhesive (PSA).
The films are prepared by spin-coating which enables an easy
thickness control via the polymer concentration of the
solution. The film thickness is determined with x-ray
reflectivity (XRR) and white light interferometry (WLI).
Grazing incidence small angle x-ray scattering (GISAXS)
provides detailed and statistically significant information
about the film morphology. Two types of lateral structures
are identified and no strong correlation of these structures
with the PSA film thickness is observed. In contrast,
prominent parameters of the probe tack test, such as the
stress maximum and the tack energy, exhibit an exponential
dependence on the film thickness.},
keywords = {Acrylates: chemistry / Adhesives: chemistry / Chemistry:
methods / Interferometry / Light / Materials Testing /
Polymers: chemistry / Pressure / Scattering, Radiation /
Stress, Mechanical / Surface Properties / X-Rays / Acrylates
(NLM Chemicals) / Adhesives (NLM Chemicals) / Polymers (NLM
Chemicals) / n-butyl acrylate (NLM Chemicals) / methyl
acrylate (NLM Chemicals)},
cin = {HASYLAB},
ddc = {540},
cid = {$I:(DE-H253)HASYLAB_-2012_-20130307$},
pnm = {DORIS Beamline BW4 (POF2-54G13) / FS-Proposal: II-20060125
(II-20060125)},
pid = {G:(DE-H253)POF2-BW4-20130405 / G:(DE-H253)II-20060125},
experiment = {EXP:(DE-H253)D-BW4-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:22817560},
UT = {WOS:000307698600027},
doi = {10.1021/am300774b},
url = {https://bib-pubdb1.desy.de/record/140186},
}