Home > Publications database > Photolysis of water-radical ions $\mathrm{H_2O^+}$ in the xuv: Fragmentation through dicationic states > print |
001 | 139445 | ||
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024 | 7 | _ | |2 ISSN |a 0556-2791 |
024 | 7 | _ | |2 ISSN |a 1094-1622 |
024 | 7 | _ | |2 ISSN |a 1050-2947 |
024 | 7 | _ | |2 WOS |a WOS:000312994700010 |
024 | 7 | _ | |2 doi |a 10.1103/PhysRevA.87.013402 |
024 | 7 | _ | |2 datacite_doi |a 10.3204/PHPPUBDB-23710 |
024 | 7 | _ | |a openalex:W1965248190 |2 openalex |
037 | _ | _ | |a PHPPUBDB-23710 |
041 | _ | _ | |a English |
082 | _ | _ | |a 530 |
100 | 1 | _ | |0 P:(DE-HGF)0 |a Pedersen, H. B. |b 0 |e Corresponding author |
110 | 1 | _ | |a DESY |b Experiments with synchrotron radiation |
245 | _ | _ | |a Photolysis of water-radical ions $\mathrm{H_2O^+}$ in the xuv: Fragmentation through dicationic states |
260 | _ | _ | |a College Park, Md. |b APS |c 2013 |
264 | _ | 1 | |3 online |2 Crossref |b American Physical Society (APS) |c 2013-01-02 |
264 | _ | 1 | |3 print |2 Crossref |b American Physical Society (APS) |c 2013-01-01 |
300 | _ | _ | |a 013402 |
336 | 7 | _ | |2 DRIVER |a article |
336 | 7 | _ | |2 DataCite |a Output Types/Journal article |
336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1518707910_16857 |
336 | 7 | _ | |2 BibTeX |a ARTICLE |
336 | 7 | _ | |2 ORCID |a JOURNAL_ARTICLE |
336 | 7 | _ | |0 0 |2 EndNote |a Journal Article |
440 | _ | 0 | |0 PERI:(DE-600)1472694-4 |a Phys. Rev. A |v 87 |x 0556-2791 |
500 | _ | _ | |3 POF3_Assignment on 2016-02-09 |
500 | _ | _ | |3 Converted on 2013-05-30 09:27 |
500 | _ | _ | |3 Converted on 2013-06-21 19:21 |
520 | _ | _ | |a The photofragmentation of the water cation $H_2O^+$ through dicationic states has been studied at 35.0 ± 0.2 nm (35.4 ± 0.3 eV) and 21.8 ± 0.2 nm (56.8 ± 0.5 eV) with a crossed ion-photon beams experiment at the free electron laser FLASH. The dissociation of the dications is found to be similar at the two wavelengths and to proceed into $O^0 + 2H^+$, $OH^+ + H^+$, and $O^+ + H_2^+$, with determined ratios $\sigma_{OH^+ + H^+}/\sigma_{O^+ + H_2^+}$= 4.2 ±0.3 and $\sigma_{OH^+ + H^+}/\sigma_{O^+ + 2H^+}$>0.7. The measured kinetic-energy releases for these processes are consistent with three-body breakup ($O^0+2H^+$) occurring mainly through the $2^3A''$ and $2^1A''$ states of $H_2O_2^+$ and two-body breakup ($OH^+ + H^+$) occurring through $X^3A''$, $1^3A′$, and $1^1A''$ states of $H_2O_2^+$, as predicted in a recent theoretical study [Gervais et al., J. Chem. Phys. 131, 024302 (2009)]. In addition to the kinetic-energy releases, we also report on fragment correlation in the three-body channel where the two protons carry the major part of the released momentum. |
536 | _ | _ | |0 G:(DE-H253)POF2-PG2-20130405 |f POF II |x 0 |c POF2-54G16 |a FLASH Beamline PG2 (POF2-54G16) |
542 | _ | _ | |i 2013-01-02 |2 Crossref |u http://link.aps.org/licenses/aps-default-license |
693 | _ | _ | |0 EXP:(DE-H253)F-PG2-20150101 |1 EXP:(DE-H253)FLASH-20150101 |6 EXP:(DE-H253)F-PG2-20150101 |a FLASH |f FLASH Beamline PG2 |x 0 |
700 | 1 | _ | |a Domesle, C. |b 1 |
700 | 1 | _ | |a Lammich, L. |b 2 |
700 | 1 | _ | |a Dziarzhytski, S. |b 3 |
700 | 1 | _ | |a Guerassimova, N. |b 4 |
700 | 1 | _ | |a Treusch, R. |b 5 |
700 | 1 | _ | |a Harbo, L. S. |b 6 |
700 | 1 | _ | |a Heber, O. |b 7 |
700 | 1 | _ | |a Jordon-Thaden, B. |b 8 |
700 | 1 | _ | |a Arion, T. |b 9 |
700 | 1 | _ | |a Förstel, M. |b 10 |
700 | 1 | _ | |a Stier, M. |b 11 |
700 | 1 | _ | |a Hergenhahn, U. |b 12 |
700 | 1 | _ | |a Wolf, A. |b 13 |
773 | 1 | 8 | |a 10.1103/physreva.87.013402 |b American Physical Society (APS) |d 2013-01-02 |n 1 |p 013402 |3 journal-article |2 Crossref |t Physical Review A |v 87 |y 2013 |x 1050-2947 |
773 | _ | _ | |a 10.1103/PhysRevA.87.013402 |g Vol. 87, p. 013402 |0 PERI:(DE-600)2844156-4 |n 1 |q 87<013402 |p 013402 |t Physical review / A |v 87 |y 2013 |x 1050-2947 |
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913 | 2 | _ | |0 G:(DE-HGF)POF3-621 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6211 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v In-house research on the structure, dynamics and function of matter |x 0 |
913 | 2 | _ | |0 G:(DE-HGF)POF3-622 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6G2 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v Facility topic: Research on Matter with Brilliant Light Sources |x 1 |
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914 | 1 | _ | |y 2013 |
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