Documents in process

The high global warming potential of CH4 makes the catalytic conversion of residual CH4 in exhaust gases vital for applications such as CH4 combus tion engines and turbines, power-to-gas or biomass plants. The most active heterogeneous catalyst system for complete CH4 oxidation at low temper atures (< 650K) in lean reaction gas mixtures (overstoichiometric oxygen content) is the class of Pd-based catalysts supported by (mixed) metal oxide supports. [...]

A search is performed for a new resonance X decaying into either a pair of Higgs bosons (HH) or into a Higgs boson and a new scalar boson Y (HY), using proton-proton collision data collected at $\sqrt{s}$ = 13 TeV, corresponding to an integrated luminosity of 138 fb$^{-1}$. This study performs a comprehensive exploitation of the bbZZ events, encompassing the following decay topologies. [...]

Combined measurements of Higgs boson production and decay rates are reported, representing the most comprehensive study performed by the CMS Collaboration to date. The included analyses use proton-proton collision data recorded by the CMS experiment at $\sqrt{s}$ = 13 TeV from 2016 to 2018, corresponding to an integrated luminosity of 138 fb$^{-1}$. [...]

Understanding the nature of active sites in heterogeneous catalysts and how to create them purposefully opens up the possibility of tailored catalyst design. Here we report mixed-valence subnanometre CoOx clusters, consisting of a few metallic Co⁰ atoms on top of Co²⁺, bound to a silicalite-1 support through lattice oxygen atoms as active species for non-oxidative propane dehydrogenation (PDH) to propene. [...]

Investigating materials under extreme pressure using diamond anvil cells (DACs) requires very small samples. X-ray diffraction studies of such samples therefore require beams focused to <5 μm. [...]

CK2α and CK2α’, two paralogous members of the human kinome, are catalytic subunits of protein kinase CK2. Together with the regulatory subunit CK2β, they form heterotetrameric holoenzymes. [...]

The success of mRNA lipid nanoparticles (LNPs) used in the COVID-19 vaccines has demonstrated the significance of pharmaceutical products utilizing nanoparticle-based drug delivery systems in global healthcare. For the assessment of the safety, efficacy, and quality of these complex, multicomponent systems, it is important to consider not only the properties of the individual components but also their colloidal organization. [...]

Recent advances in laser technologies such as x-ray free-electron lasers and high harmonic generation have led to ever-shorter light pulses that enable us to probe ultrafastnuclear and electronic dynamics in atoms and molecules. Theoretical quantum dynamics simulations are indispensable in gaining deeper insights into these ultrafastprocesses. [...]

This thesis presents a novel method for studying capillary imbibition and vapor sorption in mesoporous silicon (PSi) with white light spectroscopy. By Fast-Fourier-Transformation of thin film interference and parallel analysis of an optical microcavity within the porous layer, it achieves high precision in monitoring fluid dynamics. [...]