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@ARTICLE{Kaban:87993,
author = {Kaban, I. and Jóvári, P. and Wagner, T. and Frumar, M.
and Stehlik, S. and Bartos, M. and Hoyer, W. and Beuneu, B.
and Webb, M. A. and DESY},
title = {{A}tomic structure of ${A}s_{2}{S}_{3}-{A}g$ chalcogenide
glasses},
journal = {Journal of physics / Condensed matter},
volume = {21},
issn = {0953-8984},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {PHPPUBDB-10163},
pages = {395801},
year = {2009},
abstract = {(As(0.4)S(0.6))(100-x)Ag(x) glasses (x = 0, 4, 8,
$12 at.\%)$ have been studied with high-energy x-ray
diffraction, neutron diffraction and extended x-ray
absorption spectroscopy at As and Ag K-edges. The
experimental data were modelled simultaneously with the
reverse Monte Carlo simulation method. Analysis of the
partial pair correlation functions and coordination numbers
extracted from the model atomic configurations revealed that
silver preferentially bonds to sulfur in the As(2)S(3)-Ag
ternary glasses, which results in the formation of
homoatomic As-As bonds. Upon the addition of Ag, a small
proportion of Ag-As bonds (N(AgAs)≈0.3) are formed in all
three ternary compositions, while the direct Ag-Ag bonds
(N(AgAg)≈ 0.4) appear only in the glass with the highest
Ag content $(12 at.\%).$ Similar to the g- As(2)S(3)
binary, the mean coordination number of arsenic is close to
three, and that of sulfur is close to two, in the
As(2)S(3)-Ag ternary glasses. The first sharp diffraction
peak on the total structure factors of As(2)S(3) binary and
(As(0.4)S(0.6))(100-x)Ag(x) ternary glasses is related to
the As-As and As-S correlations.},
cin = {HASYLAB},
ddc = {530},
cid = {$I:(DE-H253)HASYLAB_-2012_-20130307$},
pnm = {DORIS Beamline X1 (POF1-550) / DORIS Beamline BW5
(POF1-550) / FS-Proposal: II-20060203 (II-20060203)},
pid = {G:(DE-H253)POF1-X1-20130405 / G:(DE-H253)POF1-BW5-20130405
/ G:(DE-H253)II-20060203},
experiment = {EXP:(DE-H253)D-X1-20150101 / EXP:(DE-H253)D-BW5-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:21832397},
UT = {WOS:000269626500015},
doi = {10.1088/0953-8984/21/39/395801},
url = {https://bib-pubdb1.desy.de/record/87993},
}