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@ARTICLE{Rebholz:460219,
      author       = {Rebholz, Marc and Ding, Thomas and Despré, Victor and
                      Aufleger, Lennart and Hartmann, Maximilian and Meyer,
                      Kristina and Stooss, Veit and Magunia, Alexander and Wachs,
                      David and Birk, Paul and Mi, Yonghao and Borisova, Gergana
                      and Castanheira, Carina da Costa and Rupprecht, Patrick and
                      Schmid, Georg and Schnorr, Kirsten and Schröter, Claus
                      Dieter and Moshammer, Robert and Loh, Zhi-Heng and Attar,
                      Andrew and Leone, Stephen R. and Gaumnitz, Thomas and
                      Woerner, Hans Jakob and Roling, Sebastian and Butz, Marco
                      and Zacharias, Helmut and Duesterer, Stefan and Treusch,
                      Rolf and Brenner, Guenter and Vester, Jonas and Kuleff,
                      Alexander I. and Ott, Christian and Pfeifer, Thomas},
      title        = {{A}ll-{XUV} {P}ump-{P}robe {T}ransient {A}bsorption
                      {S}pectroscopy of the {S}tructural {M}olecular {D}ynamics of
                      {D}i-iodomethane},
      journal      = {Physical review / X},
      volume       = {11},
      number       = {3},
      issn         = {2160-3308},
      address      = {College Park, Md.},
      publisher    = {APS},
      reportid     = {PUBDB-2021-02850},
      pages        = {031001 (1-9)},
      year         = {2021},
      abstract     = {In this work, we use an extreme-ultraviolet (XUV)
                      free-electron laser (FEL) to resonantly excite the
                      I: 4$d_{5/2}–σ^∗$ transition of a gas-phase
                      di-iodomethane (CH$_2$I$_2$) target. This site-specific
                      excitation generates a 4$d$ core hole located at an iodine
                      site, which leaves the molecule in a well-defined excited
                      state. We subsequently measure the time-dependent absorption
                      change of the molecule with the FEL probe spectrum centered
                      on the same I: 4$_d$ resonance. Using ab initio
                      calculations of absorption spectra of a transient
                      isomerization pathway observed in earlier studies, our
                      time-resolved measurements allow us to assign the timescales
                      of the previously reported direct and indirect dissociation
                      pathways. The presented method is thus sensitive to
                      excited-state molecular geometries in a time-resolved
                      manner, following a core-resonant site-specific trigger.},
      cin          = {DOOR ; HAS-User / FS-FLASH-O / FS-FLASH-B / FS-FLASH-D},
      ddc          = {530},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-FLASH-O-20160930 /
                      I:(DE-H253)FS-FLASH-B-20160930 /
                      I:(DE-H253)FS-FLASH-D-20160930},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / 6G2 - FLASH (DESY) (POF4-6G2)},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G2},
      experiment   = {EXP:(DE-H253)F-BL2-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000669051000001},
      doi          = {10.1103/PhysRevX.11.031001},
      url          = {https://bib-pubdb1.desy.de/record/460219},
}