Home > Publications database > Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry > print

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024 7 _ |a 1943-2984
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100 1 _ |a Karadeniz, Bahar
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245 _ _ |a Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry
260 _ _ |a Washington, DC
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|b American Chemical Society
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500 _ _ |a © American Chemical Society
520 _ _ |a Tetratopic porphyrin-based metal−organicframeworks (MOFs) represent a particularly interestingsubclass of zirconium MOFs due to the occurrence ofseveral divergent topologies. Control over the targettopology is a demanding task, and reports often showproducts containing phase contamination. We demonstratehow mechanochemistry can be exploited forcontrolling the polymorphism in 12-coordinated porphyriniczirconium MOFs, obtaining pure hexagonal PCN-223and cubic MOF-525 phases in 20−60 min of milling. Thereactions are mainly governed by the milling additives andthe zirconium precursor. In situ monitoring by synchrotronpowder X-ray diffraction revealed that specificreaction conditions resulted in the formation of MOF-525 as an intermediate, which rapidly converted to PCN-223 upon milling. Electron spin resonance measurementsrevealed significant differences between the spectra ofparamagnetic centers in two polymorphs, showing apotential of polymorphic Zr-MOFs as tunable supports inspintronics applications.
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700 1 _ |a Žilić, Dijana
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700 1 _ |a Huskić, Igor
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700 1 _ |a Germann, Luzia S.
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700 1 _ |a Fidelli, Athena M.
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700 1 _ |a Muratović, Senada
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773 _ _ |a 10.1021/jacs.9b10251
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