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000429646 1001_ $$aKaradeniz, Bahar$$b0
000429646 245__ $$aControlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry
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000429646 520__ $$aTetratopic porphyrin-based metal−organicframeworks (MOFs) represent a particularly interestingsubclass of zirconium MOFs due to the occurrence ofseveral divergent topologies. Control over the targettopology is a demanding task, and reports often showproducts containing phase contamination. We demonstratehow mechanochemistry can be exploited forcontrolling the polymorphism in 12-coordinated porphyriniczirconium MOFs, obtaining pure hexagonal PCN-223and cubic MOF-525 phases in 20−60 min of milling. Thereactions are mainly governed by the milling additives andthe zirconium precursor. In situ monitoring by synchrotronpowder X-ray diffraction revealed that specificreaction conditions resulted in the formation of MOF-525 as an intermediate, which rapidly converted to PCN-223 upon milling. Electron spin resonance measurementsrevealed significant differences between the spectra ofparamagnetic centers in two polymorphs, showing apotential of polymorphic Zr-MOFs as tunable supports inspintronics applications.
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000429646 7001_ $$00000-0003-2387-0853$$aŽilić, Dijana$$b1
000429646 7001_ $$aHuskić, Igor$$b2
000429646 7001_ $$aGermann, Luzia S.$$b3
000429646 7001_ $$aFidelli, Athena M.$$b4
000429646 7001_ $$aMuratović, Senada$$b5
000429646 7001_ $$00000-0002-5554-4641$$aLončarić, Ivor$$b6
000429646 7001_ $$0P:(DE-H253)PIP1018552$$aEtter, Martin$$b7
000429646 7001_ $$0P:(DE-H253)PIP1018079$$aDinnebier, Robert E.$$b8
000429646 7001_ $$aBarišić, Dajana$$b9
000429646 7001_ $$aCindro, Nikola$$b10
000429646 7001_ $$00000-0003-3688-9158$$aIslamoglu, Timur$$b11
000429646 7001_ $$00000-0002-9904-9845$$aFarha, Omar K.$$b12
000429646 7001_ $$0P:(DE-H253)PIP1026729$$aFriscic, Tomislav$$b13
000429646 7001_ $$aUžarević, Krunoslav$$b14
000429646 773__ $$0PERI:(DE-600)1472210-0$$a10.1021/jacs.9b10251$$gVol. 141, no. 49, p. 19214 - 19220$$n49$$p19214 - 19220$$tJournal of the American Chemical Society$$v141$$x1520-5126$$y2019
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