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024 7 _ |2 doi
|a 10.1080/01442350601087664
024 7 _ |2 ISSN
|a 0144-235X
024 7 _ |2 ISSN
|a 1366-591X
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082 _ _ |a 540
088 1 _ |a arXiv:physics/0609052
088 _ _ |a arXiv:physics/0609052
|2 arXiv
100 1 _ |0 P:(DE-H253)PIP1012175
|a Küpper, Jochen
|b 0
|e Corresponding author
245 _ _ |a Spectroscopy of free radicals and radical containing entrance-channel complexes in superfluid helium nanodroplets
260 _ _ |a London [u.a.]
|b Taylor & Francis
|c 2007
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500 _ _ |a VITA
520 _ _ |a The spectroscopy of free radicals and radical containing entrance-channel complexes embedded in superfluid helium nano-droplets is reviewed. The collection of dopants inside individual droplets in the beam represents a micro-canonical ensemble, and as such each droplet may be considered an isolated cryo-reactor. The unique properties of the droplets, namely their low temperature (0.4 K) and fast cooling rates (∼1016 K s−1) provides novel opportunities for the formation and high-resolution studies of molecular complexes containing one or more free radicals. The production methods of radicals are discussed in light of their applicability for embedding the radicals in helium droplets. The spectroscopic studies performed to date on molecular radicals and on entrance / exit-channel complexes of radicals with stable molecules are detailed. The observed complexes provide new information on the potential energy surfaces of several fundamental chemical reactions and on the intermolecular interactions present in open-shell systems. Prospects of further experiments of radicals embedded in helium droplets are discussed, especially the possibilities to prepare and study high-energy structures and their controlled manipulation, as well as the possibility of fundamental physics experiments.
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Merritt, Jeremy M.
|b 1
773 _ _ |0 PERI:(DE-600)2017805-0
|a 10.1080/01442350601087664
|g Vol. 26, no. 2, p. 249 - 287
|n 2
|p 249 - 287
|t International reviews in physical chemistry
|v 26
|x 1366-591X
|y 2007
856 4 _ |u http://www.tandfonline.com/doi/abs/10.1080/01442350601087664
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