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@ARTICLE{Guo:206539,
author = {Guo, Shuai and Herzig, Eva M. and Naumann, Anna and
Tainter, Gregory and Perlich, Jan and Müller-Buschbaum,
Peter},
title = {{I}nfluence of {S}olvent and {S}olvent {A}dditive on the
{M}orphology of {PTB}7 {F}ilms {P}robed via {X}-ray
{S}cattering},
journal = {The journal of physical chemistry / B},
volume = {118},
number = {1},
issn = {1520-5207},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PUBDB-2015-01003},
pages = {344 - 350},
year = {2014},
note = {(c) American Chemical Society. Post referee full text in
progress.},
abstract = {Films of the semiconducting polymer
poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]]
with $40\%$ fluorinated monomers, denoted PTB7-F40, are spin
coated out of different solvents onto PEDOT:PSS films. The
influence of the used solvents chlorobenzene,
1,2-dichlorobenzene, and 1,2,4-trichlorobenzene as well as
the influence of the additive 1,8-diiodooctane (DIO) is
probed with grazing incidence small- and wide-angle X-ray
scattering (GISAXS and GIWAXS). As seen with GISAXS, without
DIO, the films are homogeneous and show roughness
correlation with the PEDOT:PSS film surface. With DIO, an
inner film structure with a size of 50–75 nm is found and
the roughness correlations weaken. In addition, as seen in
GIWAXS, the crystalline part of the films is influenced by
the used solvent if DIO is added.},
cin = {DOOR},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {DORIS Beamline BW4 (POF2-54G13) / FS-Proposal: I-20110417
(I-20110417)},
pid = {G:(DE-H253)POF2-BW4-20130405 / G:(DE-H253)I-20110417},
experiment = {EXP:(DE-H253)D-BW4-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000329678000036},
pubmed = {pmid:24341791},
doi = {10.1021/jp410075a},
url = {https://bib-pubdb1.desy.de/record/206539},
}