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2025-10-13
15:22
[PUBDB-2025-04331] Dissertation / PhD Thesis
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Improving the performance of Co- and Ni-based pseudocapacitors
129 pp. () = Dissertation, University of Nova Gorica, 2025  GO
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2025-10-13
14:10
OpenAccess [PUBDB-2025-04329] Journal Article
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Cretaceous amber of Ecuador unveils new insights into South America’s Gondwanan forests
Amber, a fossilised resin, became widespread during the Barremian ( ~ 122 Ma), marking the onset of the Cretaceous Resinous Interval (125–72 Ma). While common in the Northern Hemisphere, amber containing terrestrial arthropod inclusions had not previously been reported from the Mesozoic of South America [...]
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2025-10-13
14:08
Embargoed OpenAccess [PUBDB-2025-04328] Journal Article
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Synthesis of luminescent dinaphthopentacene isomers and their application in OLEDs
Here we report the straightforward synthesis of a novel nanographene, syn-dinaphthopentacene. This new compound was prepared along with its isomer anti-dinaphthopentacene to compare how small structural differences may affect properties such as crystal packing, photostability, and device performance [...]
Published on 2025-08-14. Available in OpenAccess from 2026-08-14.: Download fulltextPDF Download fulltextPDF (PDFA) (additional files);

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2025-10-13
13:09
OpenAccess [PUBDB-2025-04323] Journal Article
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Pressure‐Driven Reactivity in Dense Methane‐Nitrogen Mixtures
Carbon, nitrogen, and hydrogen are among the most abundant elements in the solar system, and our understanding of their interactions is fundamental to prebiotic chemistry. CH4 and N2 are the simplest archetypical molecules formed by these elements and are both markedly stable under extremes of pressure. [...]
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2025-10-13
12:59
[PUBDB-2025-04322] Journal Article
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High-Pressure Synthesis and Characterization of the Novel Potassium Superhydride $KH_9$
Through high-pressure diamond anvil cell experiments, we report the synthesis of two novel potassium superhydrides (KH9-I and KH9-II) and investigate their structural and vibrational properties via synchrotron X-ray powder diffraction and Raman spectroscopy, complemented by density functional theory (DFT) calculations. Above 17 GPa at room temperature, KH-II and H2 react to form KH9-I; this reaction can be accelerated with temperature. [...]
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2025-10-13
11:00
OpenAccess [PUBDB-2025-04311] Journal Article
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Core-valence double ionization of carbon suboxide
We have measured the core-valence double ionization spectra of carbon suboxide above both the O 1s and C 1s edges. Following several core-valence cases known in the literature, to begin with the spectra are compared with the well-known single ionization valence photoelectron spectrum of this system, from which they surprisingly differ quite strongly [...]
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2025-10-13
10:47
[PUBDB-2025-04310] Dissertation / PhD Thesis
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Intermediate valence transition in epitaxial (111) films of strongly correlated Thulium monochalcogenidesZwischenvalenz-Übergänge in epitaktischen (111) Filmen aus stark korrelierten Thulium-Monochalkogeniden
Wuerzburg : Universität Würzburg 158 pp. () = Dissertation, Julius-Maximilians-Universitaet Wuerzburg, 2024  GO
Fundamental insights into complex quantum phases of many-body systems can be ob-tained by the investigation of the underlying particle interactions. The variety of compet-ing interactions between particles involved determines their behaviour in these quantumphases. [...]
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2025-10-13
10:40
OpenAccess [PUBDB-2025-04309] Journal Article
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Limited Surface Oxide Growth as a Prerequisite for Stabilizing Low-Loading Iridium Electrodes for PEM Water Electrolysis
ACS catalysis 15(8), 6098 - 6113 () [10.1021/acscatal.4c07864]  GO
As the demand for hydrogen production increases, the economic viability and stability of Ir-based catalysts are crucial in proton exchange membrane water electrolysis (PEMWE). In this study, stable low-loading Ir electrodes (0.2 mgIr cm–2) with nanometer-thick electrodeposited layers are prepared on Pt-deposited Ti felts [...]
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2025-10-13
10:20
[PUBDB-2025-04307] Journal Article
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High-Pressure Mg$_3$Cl$_7$ Synthesized in a Diamond Anvil Cell as a Polar Metal with Second-Harmonic Generation
Polar metals have attracted growing interest due to both their significance in fundamental science and their potential functionalities. Here, we report the discovery of a novel polar metal, magnesium chloride Mg$_3$Cl$_7$, in which the metallicity of the polar structure is uniquely driven by attractive halogen interactions [...]
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2025-10-13
10:17
[PUBDB-2025-04306] Journal Article
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High-Pressure Synthesis of Two Pb$_3$(C$_3$N$_6$) Polymorphs Featuring Fully Deprotonated [C$_3$N$_6$]$_6$– Melaminate Anions
Graphitic carbon nitride (g-C3N4), melamine, and their derivatives are of significant interest due to their diverse structural properties and potential applications in catalysis, energy storage, and materials science. In this study, two new compounds, both with the Pb3(C3N6) chemical formula, were synthesized at pressures of 40(2) to 48(2) GPa through a direct reaction between Pb, C and N2, or Pb and C6N4, in laser-heated diamond anvil cells. [...]
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