FS-SMP

Latest additions:
2018-01-11
16:41
OpenAccess [PUBDB-2018-00557] Journal Article
; ;
Structural determination and population transfer of 4-nitroanisole by broadband microwave spectroscopy and tailored microwave pulses
ddc:540
The rotational spectrum of 4-nitroanisole was recorded via chirped-pulse Fourier transform microwave spectroscopy in the frequency range of 2-8 GHz. The spectra of the parent molecule and all of its $^{13}$C-, $^{15}$N-, and $^{18}$O-monosubstituted species in their natural abundance were assigned, and the molecular structure was determined using Kraitchman’s equations as well as a least-square fitting approach [...]
OpenAccess: Download fulltextPDF Download fulltextPDF (PDFA);

Detailed record - Similar records
2018-01-11
16:16
OpenAccess [PUBDB-2018-00548] Journal Article
; ;
On the structural intricacies of a metabolic precursor: Direct spectroscopic detection of water-induced conformational reshaping of mevalonolactone
ddc:540
We use high-resolution rotational spectroscopy to investigate the structural intricacies of the lactone form of mevalonic acid, precursor of the mevalonate pathway. By combining microwave spectroscopy with supersonic expansions and quantum-chemical calculations, we determine the two most stable conformations of the precursor. [...]
OpenAccess: Download fulltextPDF Download fulltextPDF (PDFA);

Detailed record - Similar records
2018-01-11
11:08
Embargoed OpenAccess [PUBDB-2018-00456] Journal Article
; ; ; et al
Capturing the Elusive Water Trimer from the Stepwise Growth of Water on the Surface of the Polycyclic Aromatic Hydrocarbon Acenaphthene
ddc:530
Polycyclic aromatic hydrocarbons (PAHs) are key players in reaction chemistry. While it is postulated that they serve as a basis for ice grains, there has been no direct detection of PAHs in astronomical environments. [...]
Published on 2017-11-07. Available in OpenAccess from 2018-11-07.: Download fulltextPDF Download fulltextPDF (PDFA); Restricted: Download fulltextPDF Download fulltextPDF (PDFA);

Detailed record - Similar records
2017-09-07
07:36
OpenAccess [PUBDB-2017-10447] Journal Article
; ; ; et al
Cold Snapshot of a Molecular Rotary Motor Captured by High-Resolution Rotational Spectroscopy
ddc:540
We present the first high-resolution rotational spectrum of an artificial molecular rotary motor. By combining chirped-pulse Fourier transform microwave spectroscopy and supersonic expansions, we captured the vibronic ground-state conformation of a second-generation motor based on chiral, overcrowded alkenes. [...]
OpenAccess: Download fulltextPDF Download fulltextPDF (PDFA);

Detailed record - Similar records
2017-09-07
07:32
Embargoed OpenAccess [PUBDB-2017-10446] Journal Article
; ; ; et al
Coherent Enantiomer-Selective Population Enrichment Using Tailored Microwave Fields
ddc:540
We report the experimental demonstration of coherent enantiomer-selective enrichment of chiral molecules by employing a novel microwave five-pulse scheme. Our results show that enantiomers can be selectively transferred to a rotational level of choice by applying sequences of resonant microwave pulses in a phase- and polarization-controlled manner. [...]
Published on 2017-09-27. Available in OpenAccess from 2018-09-27.: Download fulltextPDF Download fulltextPDF (PDFA); Restricted: Download fulltextPDF Download fulltextPDF (PDFA);

Detailed record - Similar records